Complexity behind CO2Capture on NH2-MIL-53(Al)
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چکیده
منابع مشابه
Synthesis and post-synthetic modification of MIL-101(Cr)-NH2 via a tandem diazotisation process.
The functionalised metal-organic framework MIL-101(Cr)-NH(2), containing 2-aminobenzene-1,4-dicarboxylate as the linker, has been synthesised. A new tandem post-synthetic modification strategy involving diazotisation as the first step has been developed and used to introduce halo- and azo dye-functional groups into the pores.
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The three-dimensional (3D) microporous titanium aminoterephthalate MIL-125-NH₂ (MIL: Material of Institut Lavoisier) was successfully isolated as monodispersed nanoparticles, which are compatible with intravenous administration, by using a simple, safe and low-cost synthetic approach (100 °C/32 h under atmospheric pressure) so that for the first time it could be considered for encapsulation and...
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For the first time an azo functionality was covalently introduced into a MOF by post-synthetic modification. The reaction of Cr-MIL-101-NH(2) with p-phenylazobenzoylchloride (1) and 4-(phenylazo)phenylisocyanate (2) as the reactants led to the compounds Cr-MIL-101_amide and Cr-MIL-101_urea, with the azo groups protruding into the mesoporous cages. XRPD and N(2) sorption measurements confirm the...
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Palladium nanoparticles have been immobilized into an amino-functionalized metal-organic framework (MOF), MIL-101Cr-NH2, to form Pd@MIL-101Cr-NH2. Four materials with different loadings of palladium have been prepared (denoted as 4-, 8-, 12-, and 16 wt%Pd@MIL-101Cr-NH2). The effects of catalyst loading and the size and distribution of the Pd nanoparticles on the catalytic performance have been ...
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Karoline Wiesner, ∗ Mile Gu, Elisabeth Rieper, and Vlatko Vedral 4, 2 School of Mathematics, University of Bristol, University Walk, Bristol BS8 1TW, United Kingdom Centre for Quantum Technologies, National University of Singapore, 3 Science Drive 2, S15-03-18, Singapore 117543, Singapore Atomic and Laser Physics, Clarendon Laboratory, University of Oxford, Parks Road, Oxford OX1 3PU, United Ki...
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ژورنال
عنوان ژورنال: Langmuir
سال: 2011
ISSN: 0743-7463,1520-5827
DOI: 10.1021/la1045207